OPTIMIZATION OF TITANIUM NITRIDE FILM SYNTHESIS: CORRELATIONS BETWEEN THE STRUCTURE / MICRO-HARDNESS AND DEPOSITION CONDITIONS
DOI:
https://doi.org/10.24193/subbphys.2018.07Keywords:
TiN films, DC sputtering, XRD,hardness.Abstract
The DC sputtering method based on the variation of the potential of target function of nitrogen flow rate, for the deposition of titanium nitride (TiN) films, with the elementary chemical composition close to the stoichiometric one is presented. The process control method used in these experiments is the identification of the nitrogen flow required for the deposition of stoichiometric TiN layers by using the target potential as the reference parameter. The effects of the nitrogen flow, polarization voltage and discharge current on the structure, microstructure and micro-hardness of TiN films was studied.References
L. Hultman, S.A. Barnett, J.E. Sundgren, J.E. Greene, J. Cryst. Growth 92, 639–656 (1988).
W.D. Sproul, P.J. Rudnik, M.E. Graham, S.L. Rohde, Surf. Coat. Technol. 43, 270–278 (1990).
M. L. Kuruppu, G. Negrea, I. P. Ivanov, and S. L. Rohde, Journal of Vacuum Science and Technology A, 16(3),1949-1955 (1998).
P. Patsalas, C. Charitidis, S. Logothetidis, Surf. Coat. Technol. 125, 335–340 (2000).
P.H. Mayrhofer, F. Kunc, J. Musil, C. Mitterer, Thin Solid Films 415, 151– 159 (2002).
G. Abadias, P. Guerin, Appl. Phys. Lett. 93, 111908 (2008).
S. Mahieu, D. Depla, J. Phys. D: Appl. Phys. 42, 053002 (2009).
S. Mahieu, P. Ghekiere, D. Depla, R. De Gryse, Thin Solid Films 515, 1229 (2006).
J.A. Thornton, J. Vac. Sci. Technol. A 4, 3059–3065 (1986).
A. Anders, Thin Solid Films 518, 4087–4090 (2010).
R.Kröger, M.Eizenberg, C.Marcadal, L.Chen, J.Appl.Phys.91, 5149–5154 (2002).
Z.Peng, H.Miao, L.Qi, S.Yang, C.Liu, ActaMater.51, 3085–3094 (2003).
R.W.Poon, J.P.Ho, X.Liu, C.Chung, P.K.Chu, K.W.Yeung W.W. Lu, K.M.Cheung, Thin Solid Films 488, 20–2 (2005)
N.K.Ponon, D.J.Appleby, E.Arac, P.King, S.Ganti, K.S.Kwa, A. O'Neill, Thin Solid Films 578,31–37 (2015)
T.-S.Yeh, J.-M.Wu, L.-J.Hu, Thin Solid Films 516, 7294–7298 (2008).
B. Window, Surface and Coatings Technology, 81(1), 92-98 (1996).
J. Musil, S. Kadlec, J. Vyskočil, V. Valvoda, Thin Solid Films, 167(1-2), 107-120 (1988).
M. Ohring, “The Materials Science of Thin Films”, Academic Press, New York, (1992).
J. -E. Sundgren, B.O. Johansson, A. Rockett, S.A. Barnett, J.E. Greene, „American Institute of Physics- Conference Proceedings”, 149, 95-115 ,(1996).
J.C. Oliveira, F. Fernandes, R. Serra, A. Cavaleiro, Thin Solid Films 645, 253-264 (2018). 21. А А Kozin, V I Shapovalov, V V Smirnov, А S Useinov,К S Kravchuk, Е V Gladkikh, А V Zavyalov and А А Morozova , IOP Conf. Series: Journal of Physics: Conf. Series 872 (2017) 012019
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2018 Studia Universitatis Babeș-Bolyai Physica
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.